Advances in Detailed Reaction Mechanisms, Volume 3: Reactions of Importance in Synthesis presents the development, discoveries, and understanding of reactions of importance in synthesis. This book discusses the significance of the reaction to organic synthesis. Organized into seven chapters, this volume begins with an overview of the effects of Lewis acids, aldehyde structure, and addition order upon the diastereoselectivity. This text then discusses the origin of the differences in reactivity and energy between the substrate and transition state conformations. Other chapters consider the influence of organometallic chemistry on the development of methodology in organic synthesis. This book discusses as well the diversity of possible facially dissymmetric dienes and dienophiles, which can be persuaded to undergo a Diels–Alder reaction. The final chapter deals with the variety of methods for the construction of carbocyclic rings. This book is a valuable resource for industrial chemists, graduate students, postdoctoral fellows, and those teaching specialized topics to graduate students.